| INTUMESCENT PRODUCTS AND FIRE PROTECTION SYSTEMS
Introduction to fire prevention
Fires and blazes
1. Early propagation and sparks
2. Flash over
3. Blaze
4. Cooling down and extinguishing
Fire hazard assessment
Conclusions

Fires and blazes :
A
blaze is defined as a reaction to combustion which occurs in
a violent and uncontrollable way. More precisely, we can use
the word blaze in the case of undesired combustion, uncontrollable
by man, that takes place in locations not originally designed
for these purposes and that involves combustible materials not
originally intended for this purpose, caused by the addition
of a sudden burst of energy.
In
our modern industrial society, combustible materials are in
abundance and consequentially, possible sources of sparks are
many.
Fire
is fed only when there is an adequate quantity of comburent,
generally the oxygen contained in the air, and continues until
its concentration dips below 14% (this figure vary with the
type of combustible material).
Some materials and substances contain a sufficient quantity
of oxygen in their molecular make up to burn without an external
source of oxygen. The most well-known of these are explosive
substances and cellulose.
When
fire and flames (the latter considered the principal vehicle
of propagation) develop due to either accidental or malicious
reasons, a blaze could be ensue: there are four phases that
characterise a blaze, defined by temperature and time factors.
1. Early propagation or sparks :
The
increase in temperature is very slow and almost linear, due
to the small quantities of combustible material involved and
the great heat dispersion in the still cold environment.
2. Flash over :
The
temperature increases and grows exponentially. Generally, the
FLASH OVER phase results temperatures that rise until reaching
500/600 °C over a period of time that can vary from 5 to
25 minutes, depending on the type of combustible material and
especially on the quantity of comburent available.
The
FLASH OVER phase is considered the point of transition between
the combustion and flame phases to the blaze phase.
3. Blaze :
In
this phase, all the flammable material becomes involved in the
combustion and the temperature begins to soar, fed by the significant
quantity of heat produced. The dispersion into the environment
is now limited while the transmission of heat through the walls
and ceilings begins to gain greater importance, caused by the
enormous difference in temperature between the dividers and
the external environment.
The
duration of this phase depends essentially on the quantity of
combustible material present and especially on the quantity
of comburent.
Generally,
a total blaze is characterised by temperatures that exceed 900°C,
at times reaching 1100°C, and the increase in temperature
remains constant until a theoretical equilibrium is achieved
between the room involved in the blaze and the external environment.
The
blaze phase is the one that results in the greatest risks. These
hazards include the possibility of deterioration or collapse
of the structures, the possible spread of the fire to surrounding
areas by flames that escape from doors and windows, the considerable
production of sparks and incandescent fragments that can be
transported by the wind towards new combustible products, and
above all, the great quantity of flammable gas produced that
can spark as soon as it is released from the area involved thanks
to availability of new comburent.
This latter hazard is well-known and much feared by emergency
fire workers, representing one of the most frequent causes of
injury to persons and the spread of fire to distant areas.
4. Cooling down and extinguishing :
The
combustible material begins to be depleted while the heat dispersion
(through walls and openings) becomes more important. In this
phase the temperatures begin to drop with an initially slow
and regular progression and then increasingly more rapid until
a temperature of 200/300 °C is reached . It is clear that the
progression of the blaze, while seemingly easy to describe,
is really quite complex and influenced by many conditions that
we are summarising below :
- Type, quantity, weight, and placement of the combustible material
- Dimensions and layout of the zone involved in the blaze
- Openings and pluggings/closures
- Contribution of the comburent ( wind, amount of air available, moisture)
Type and number of causes of the sparks.
Fire hazard evaluation :
A
blaze, by definition uncontrollable and undesired, is a greatly
feared hazard that can be reduced.
Through risk analyses, by assessing the available data, we seek
to understand the probabilities of a blaze developing. Risk
of fire can be defined simply and easily as the product of the
likelihood of the event occurring and the consequences of this
event, according to a simplified formula:
BR
(blaze)= F x M
Where: BR
is the Risk of blaze, F is the frequency and M is the magnitude
of the consequences.
Therefore,
would seem clear that to limit the risk of blaze it is necessary
to intervene on the factors that make it up, namely, on the
frequency and limiting the consequences.
Conclusions
SIX ITALIA has a range of products designed to intervene on one very important factor :
" LIMITING THE DAMAGE IN CASE OF FIRE "
In
fact, with the range of intumescent and expanding products available,
SIX ITALIA can intervene by coating and covering the supporting
structures and increasing the resistance of the structures before
the collapse temperature is reached.
Among our structure protection products, it is important to
remember intumescent bicomponent epoxy paint. EPOSIX BRD is
ideal for structures in lightweight alloys and steel. This system
enhances the fire protection qualities, while maintaining the
distinctive characteristics of the epoxy system unaltered, namely
the excellent adhesion to the surface and good mechanical resistance.
EPOSIX SM is an expanding product with excellent resistance
to external factors that doesn't require water-proof protection.
The product offers excellent fire protection characteristics
and has been formulated with acoustic muffling characteristics.
SIX ITALIA also produces a water-based intumescent product,
EPOSIX AV, and a solvent-based intumescent product, EPOSIX S.
SIX
ITALIA offers a series of panels designed with revolutionary
technology for insulating bulkheads or dividing walls with R.E.I.
resistance, using the new technologies and new synergies with
panels that do not contain glass wool or rock wool fibres.
The
SIX TH 2459 panel is composed of a blend of organic fibres with
outstanding resistance against high temperatures, SIX FIRE XJ
456 and SIXFIRE XJ 457 panels are based on inorganic extenders
and cellulose fibres with extremely good mechanical resistance,
ideal for achieving heat resistance in structures subjected
to high compression that should never be exposed to direct flames.
SIX FIRE XJ 459 is a rigid panel composed of inorganic lamellar
extenders and silicon resins, ideal for protection against high
temperatures and direct exposure to flames. SIX FIRE XJ 458
is a sublimable panel.
To complete the range of protection products, SIX ITALIA has
designed a system of expanding barriers for sealing in case
of fire cable channels, pipe channels or holes in walls that
must have R.E.I. fire resistance characteristics. The product
is composed of a 20 mm thick sheet called SIX FIRE 011 P. This
special sheet is easy to work with and can take on any number
of geometric shapes without limiting the designer or installation
technician in any way. It can be modelled with common woodworking
equipment.
The product must always be installed between rigid walls. SIX
ITALIA can also provide the system already measured and outlined
as per customer requests.
Completing
the range of barriers, the SIX FIRE 020 acrylic sealer in cartridge
for sealing joints and expanding grills and SIX FIRE GRILL for
sealing ventilation ducts.
If
you need further information or engineering testing statistics
in order to make the correct choice of materials and thickness
dimensions, our technical assistance staff and laboratories
can help.
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